What to check when the stack voltage behaves oddly. Voltage symptoms come in two kinds, and the cause is usually in the external loop rather than in the stack. Visible symptoms such as leaks, an unstable return or a falling level are gathered in one table.
Repair and replacement of external BoP components is yours. We interpret the stack's behaviour and judge whether stack service is needed.
- FirstJudge the hazard, then make it safe
- One at a timeOne change, then re-check
- RestartingFrom low current
First timeStart with the order-of-checks section. Jumping straight to the symptoms skips making the area safe.
Done this beforeFind the line for what you are seeing in the find-by-symptom table. For a voltage symptom, go to symptom A or B depending on whether it went up or down.
On this pageThe order of checks
The order of checks
- Stop and assess the hazard level.
- Any sign of a hydrogen leak, fire, arcing, a burning smell, severe overheating or uncontrolled electrolyte leakage means stop at once and follow the emergency section of the safety chapter.
- Make it safe before touching anything.
- Ramp the stack current down to 0 A, then turn off the DC output.
- Electrically isolate the DC supply from the stack and apply your site procedure to prevent accidental re-energisation.
- Secure the external loop: confirm the vent and relief lines are safe and unobstructed, and manage residual pressure and electrolyte by your site procedures.
- Record the as-found condition.
- Record at minimum the stack current and voltage and the electrolyte flow and temperature.
- Add hydrogen flow, pressure and purity and oxygen purity if you measured them.
- Write down what you observed too: pump noise or cavitation, gurgling, an unstable wet outlet return, unusual vent behaviour, visible leakage.
- Check the most likely external causes.
- Flow and heat: valves open, tubing not kinked or blocked, no trapped air, tank level adequate; the filter not clogged if you use one, and cooling available at the heat exchanger.
- Wet outlet and backpressure: no restriction or blockage in the OUT line, no kinks or pinches, and a stable return to the tank.
- Electrical: DC cables tight, no discolouration or overheating marks, correct polarity and clean terminal contact.
- Vent and relief: outlets not blocked, iced or covered, and nothing placed in front of them.
- Apply one corrective action at a time.
- Change one thing, check whether the symptom improves, then change the next. Change two together and you lose which one it was.
- When you restart, begin at low current and confirm stable flow and a stable voltage trend before ramping up.
- Know when to stop.
- If the issue persists, repeats or suggests hardware damage, stop operating and contact us.
- If you are unsure about the vent and relief routing, backpressure or the safe limits, ask us before continuing.
- Document the outcome.
- Write down what you changed and what happened. It prevents repeating the same misdiagnosis and speeds up our reply if you do contact us.
Find by symptom
Find the line for what you see, take the first action, then go to the section in the right-hand column. Lines run from most to least severe.
| What you see | Suspect first | First action | Details |
|---|---|---|---|
| Signs of a hydrogen leak, fire, arcing, a burning smell, severe overheating | — | Stop at once and follow the site emergency procedure | Safety · emergency |
| A vent blocked or iced | Condensate in the vent line | Keep people away from the discharge. Do not touch the blockage until the line is depressurised and isolated | Safety · emergency |
| Hydrogen in oxygen above 2% | Gas crossing the membrane | Stop electrolysis and shut down normally. Do not restart until the cause is found | Maintenance · electrolyte |
| Current drops on its own with no setting change, and voltage sits at the supply limit | One cell's voltage running away | Stop. Do not keep restarting | Symptom A · 5 |
| Voltage rising fast at the same current | Low temperature, dilute electrolyte, low flow | Reduce current or stop, then check temperature, concentration and flow | Symptom A |
| Voltage falling fast at the same current | High temperature, concentrated electrolyte, low flow | Reduce current or stop, then check temperature, concentration and flow | Symptom B |
| Temperature keeps climbing although cooling is available | Poor circulation, not enough cooling | Reduce current or stop | Operation · watch |
| Wetness or white crystals around a port or fitting | A loose fitting, tubing weight on a port | Stop, fix the cause, then resume. Wipe crystals off with a damp cloth | Maintenance · cleaning |
| The OUT return gurgles or keeps breaking | Line routing, back-pressure, trapped gas | Correct the routing and back-pressure before continuing | Operation · watch |
| Pump cavitation noise, or the flow wanders | Low tank level, air in the loop | Stop, correct the level, then bleed the air | Operation · level |
| Moisture from the H2 port tests alkaline on pH paper | Electrolyte crossing the membrane to the hydrogen side | Re-check during stable running. If it persists, contact us with your records | Maintenance · electrolyte |
| Concentration falls again after a change | KOH escaping somewhere | Find the escape path first. Do not just keep changing it | Maintenance · electrolyte |
Symptom A: the voltage rises rapidly
At the same current the stack voltage climbs quickly or sits unusually high. Work through the four causes from the top.
1. The electrolyte temperature is too low
- Verify the temperature reading and confirm the heater is running: power, status, setpoint.
- Bring the temperature back into the normal range, typically around 50 °C.
- If the heater is not working or the temperature cannot be restored, stop and repair or replace the heater.
- If the voltage stays abnormal after the temperature is restored, contact us.
2. The electrolyte is too dilute
- Confirm the electrolyte specification is 0.1 M KOH and review the recent DI water make-up and refill history.
- If dilution is suspected, stop and replace it with fresh 0.1 M electrolyte.
- Restart at low current and confirm a stable voltage trend before ramping up.
- If the abnormal voltage persists with fresh electrolyte, contact us.
3. Internal crossover or membrane damage is suspected
- Stop operating.
- Record the evidence: the electrolyte level trend, the DI water make-up events, and the stack current and voltage.
- Contact us with those records. This is not something you can resolve on site.
4. The electrolyte flow is low or unstable
- Confirm the pump is powered and commanded on: the indicator or controller status, and the fuse or breaker where applicable.
- If the pump is on but there is no flow, it does not start reliably, or it behaves abnormally, stop and repair or replace it before resuming.
- Confirm all the relevant valves are open.
- Remove obvious restrictions: straighten kinked tubing, clear blockages, and check or clean the filter if you have one.
- Remove air from the loop and make sure the pump is properly primed.
- Restore a stable flow, 4 L/min as recommended.
5. A single cell voltage shoots up
- If you measure individual cell voltages, one cell climbs far above the others. If you do not, the stack voltage reaches the supply's limit and the current falls by itself although no setting was changed.
- In our tests a slow rise of stack voltage at the same current appeared first, 10–24 hours before the stop.
- Stop operating and do not restart repeatedly. Send us the current and voltage trends, and the cell voltages if you record them.
Symptom B: the voltage falls rapidly
At the same current the stack voltage drops quickly or sits unusually low. The causes fall on the opposite side from symptom A.
1. The electrolyte temperature is too high
- Verify the temperature reading.
- Restore temperature control: confirm cooling is available at the heat exchanger and the circulation is working.
- If the temperature cannot be controlled, stop and service or repair the external cooling and circulation equipment.
2. The electrolyte is too concentrated
- Check the tank level and verify the DI water make-up is working.
- Correct the electrolyte back to specification, 0.1 M KOH, by your site procedure.
- Restart at low current and confirm a stable voltage trend before ramping up.
3. The electrolyte flow is low or unstable
- Work through it the same way as cause 4 under symptom A: the pump, the valves, restrictions, trapped air, and restoring the flow.
4. An abnormal stack condition is suspected
- If the voltage stays unusually low after temperature, concentration and flow are all restored, stop operating.
- Record the evidence and contact us: the stack current and voltage trend, the electrolyte temperature, the flow, and the recent maintenance history.
When to contact us
- Abnormal voltage behaviour persists after you have restored the electrolyte flow, temperature control and condition.
- Leakage recurs despite correcting the fittings and tubing and confirming material compatibility.
- You suspect damage to the stack hardware: the ports, end plates, compression hardware or terminals.
- The same problem persists or recurs under normal operating conditions and the symptom guide does not resolve it.
- You are planning non-standard operation and want the safe limits and recommended practice confirmed.
What to send
Having the following ready speeds up diagnosis. If you kept the record at the end of the quick-start chapter, half of it is already done.
| Group | Contents |
|---|---|
| Identification | Model (HXS-2) and serial number |
| Conditions at the time | Stack current and voltage, electrolyte flow and temperature. If measured, hydrogen flow, pressure and purity, and oxygen purity |
| Symptom | What you saw, and when: during start-up, while ramping, in steady running, or during shutdown |
| Installation | External loop layout (tank, pump, heat exchanger), routing of the IN, OUT and H2 lines including the wet-outlet return, and any vent and relief routing |
| History and changes | Electrolyte specification and change date, the water quality used, and anything changed recently (new stack, new electrolyte, piping, a replaced component) |
| Evidence | Photos of the terminals, any leak points and the overall routing. Logs or screenshots of current, voltage, temperature and flow around the event |
Before confirming a return we may ask for more data or troubleshoot remotely first. Once a return is confirmed we send packing and shipping instructions. Draining and packing the stack so it does not leak or corrode in transit is yours to do.
What this chapter is based on
- HXS-2 datasheetPDF · 1.3 MB
- HXS-2 outline drawingPDF · 481 KB
- Stack integration guidePDF · 449 KB
- HXS-2 user manualOn request
Ask the engineer who built it
If your case is not covered here, send us the operating condition and what you observed. The engineer who designed the system answers directly.