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Running an electrolyzer stack at 10 barg: what changes in cell voltage, crossover and long-term operation

2026.10.24

Raise the pressure only as far as you need. At 10 barg cell voltage goes up by about 30 mV per cell, which is small, but hydrogen in oxygen grows faster once pressure passes 3 barg. Measured on our 2 kW stacks, with the long-term record so far.

Running an electrolyzer stack at 10 barg: what changes in cell voltage, crossover and long-term operation

Running the hydrogen outlet at 10 barg lets you supply low-pressure storage or a downstream gas line without a compressor. Whether to keep a compressor is covered in our article on compressors. This article looks at what changes inside the stack once you have chosen pressurised operation, using measurements on our 2 kW, 23-cell stacks.

The short answer: raise the pressure only as far as you need. The voltage cost is small, but above 3 barg crossover starts to grow faster.

  • Set the outlet pressure to what you actually need. If 3 barg or less will do, there is little reason to go higher.
  • Take the voltage cost as about 30 mV per cell. It is almost the same at your operating current as at rated 50 A.
  • Check crossover at the pressure you will run. In our measurements the increase per bar grew above 3 barg.
  • Ask separately for a degradation rate at pressure. The 10 barg on a datasheet is a pressure rating, not a lifetime condition.
Three things that change at 10 barg: cell voltage, crossover and the long-term record.
Three things that change at 10 barg: cell voltage, crossover and the long-term record.

Cell voltage rises by about 30 mV per cell

We ran the same HXS-2 23-cell stack at ambient and at 10 barg, in 0.1 M KOH at 50 °C. During the sweep back-pressure fell from 10.4 to 7.3 barg, so the 10 barg values are corrected to 10 barg.

CurrentAmbient cell voltage10 barg cell voltageDifference per cellRelative to ambient
20 A1.584 V1.613 V29 mV1.8%
30 A1.610 V1.640 V30 mV1.9%
40 A1.634 V1.663 V29 mV1.8%
50 A1.657 V1.685 V28 mV1.7%
60 A1.678 V1.705 V26 mV1.6%
Cell voltage at ambient and at 10 barg, 20 to 62 A.
Cell voltage at ambient and at 10 barg, 20 to 62 A.

From 20 A to 62 A the difference stayed at 26 to 31 mV per cell. The higher the pressure of the hydrogen produced, the higher the minimum voltage needed to split water; the Nernst equation puts it at about 33 mV per cell at 50 °C and 10 barg. That difference does not depend on current, which matches what we measured.

As a percentage it is slightly larger at low current, because the difference is similar while the cell voltage itself is lower. If you plan long periods at part load, work out power consumption from the percentage at your operating current rather than the 1.7% at rated current.

Crossover grows faster above 3 barg

In AEM electrolysis, some of the hydrogen made at the cathode crosses the membrane and mixes into the oxygen at the anode. This is crossover, tracked as hydrogen in oxygen. The higher the hydrogen-side pressure, the more hydrogen crosses.

On a different HXS-2 23-cell stack we raised the pressure from 0 to 6 barg in 1 bar steps. Below are rated load and 40% load from the 49 points measured from 50 A down to 20 A at each pressure.

Hydrogen-side pressureRated load (50 A)40% load (20 A)
0 barg (ambient)0.39%0.66%
1 barg0.37%0.71%
2 barg0.43%0.81%
3 barg0.52%1.00%
4 barg0.66%1.28%
5 barg0.81%1.54%
6 barg0.98%1.75%
Hydrogen in oxygen by hydrogen-side pressure, 0 to 6 barg.
Hydrogen in oxygen by hydrogen-side pressure, 0 to 6 barg.

From 0 to 2 barg the rated-load concentration rose by only 0.04 percentage points. Above 3 barg it rises by 0.14 to 0.17 points per bar, and by more than 0.2 points per bar at 40% load. That is why, if 3 barg or less is enough for your outlet, there is little reason to run higher.

It did not rise in proportion to pressure. From 0 to 6 barg absolute pressure goes from about 1 bar to 7 bar, seven times, while the concentration went from 0.39% to 0.98%, 2.5 times. Some hydrogen crosses at ambient too.

This test stopped at 6 barg, so the table cannot tell you the values between 6 and 10 barg. How the concentration changes as load drops is covered in a separate article.

Related

Too early for a degradation rate

The constant-current long-term run at 10 barg and 50 A uses the stack from the voltage comparison above, in 0.1 M KOH at 50 °C. As of 24 October 2026 it stands at 1,768 hours, counting only the time 50 A was flowing.

ItemStart24 October
Cell voltage1.691 V1.823 V
Hydrogen in oxygen1.00%1.38%
Cell voltage and hydrogen in oxygen over the 10 barg long-term run.
Cell voltage and hydrogen in oxygen over the 10 barg long-term run.

We have not converted the voltage rise into a degradation rate. The run was stopped for inspection along the way, so it is not one continuous curve, and the early fast-rising part is still mixed in. On our ambient long-term run the slope took about 1,200 hours to settle. Once enough hours have built up since the last restart, we will calculate a rate from that period and publish it.

Hydrogen in oxygen is creeping up but is below our 2% control limit. If you compare this with our 3,000-hour cumulative record, note that the ambient run used 0.3 M KOH at 40 °C.

Related

What to check when evaluating pressurised operation

ItemReason
The outlet pressure you actually needAbove 3 barg the increase in crossover grows
Voltage difference over your operating current rangeAt part load the percentage is larger than at the rated point
Crossover measured by pressureA single point at rated pressure does not show the operating range
Hours and conditions of a pressurised long-term runAn ambient durability record cannot be carried over to pressure

In short, the voltage cost of 10 barg is small, about 30 mV per cell. Crossover is what needs attention, and above 3 barg it grows faster, so set the outlet pressure to what the application needs. Crossover between 6 and 10 barg and the long-term degradation rate under pressure are still being confirmed.

Related

Frequently asked questions

How much more power does running at 10 barg take?

About 26 to 31 mV more per cell at the same current: 1.7% at rated 50 A and 1.8% at 20 A relative to ambient. Stack DC power rises by that percentage at the same current. Energy per kilogram of recovered hydrogen also depends on crossover losses and auxiliary power.

Does raising pressure reduce hydrogen output?

Output is set by current, so at constant current it stays almost the same. More hydrogen does cross to the oxygen side and is not recovered; in our measurements at 6 barg and rated load that was about 0.5% of production.

Can I estimate 10 barg crossover from the 6 barg figures?

We would not. Nothing above 6 barg was measured in this test and values differ from stack to stack. Ask for figures measured at 10 barg.

Were all the tests run on the same stack?

Two stacks. The voltage comparison and the 10 barg long-term run used the same HXS-2 23-cell stack; the crossover measurements used a different one. So we do not read the long-term crossover value as an extension of the pressure table.

Can I get the raw data?

Yes, on request: voltage and current logs, gas concentration logs and the operating conditions.